CSI: Miami
The show follows Crime Scene Investigators working for the Miami-Dade Police Department as they use physical evidence, similar to their Las Vegas counterparts, to solve grisly murders. The series mixes deduction, gritty subject matter, and character-driven drama in the same vein as the original series in the CSI franchise, except that the Miami CSIs are cops first, scientists second.

Season 4 · Episode 18 ·
Double Jeopardy
After a man is found not guilty of his wife's murder the CSI team finds evidence to the contrary.
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Episode 18 of season 4 of CSI: Miami: “Double Jeopardy”. Aired 2006-03-13. Watch it online free on ZapFlix.