Babylon 5
Babylon 5 is a five-mile long space station located in neutral space. Built by the Earth Alliance in the 2250s, its goal is to maintain peace among the various alien races by providing a sanctuary where grievances and negotiations can be worked out among duly appointed ambassadors. A council made up of representatives from the five major space-faring civilizations - the Earth Alliance, Minbari Federation, Centauri Republic, Narn Regime, and Vorlon Empire - work with the League of Non-Aligned Worlds to keep interstellar relations under control. Aside from its diplomatic function, Babylon 5 also serves as a military post for Earth and a port of call for travelers, traders, businessmen, criminals, and Rangers.

Season 2 · Episode 7 ·
Soul Mates
Londo summons his three wives to Babylon 5 so he can divorce two of them, Talia gets a visit from her obnoxious ex-husband - the only man ever to leave the PSI Corps, and Delenn has her first bad hair day.
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Episode 7 of season 2 of Babylon 5: “Soul Mates”. Aired 1994-12-14. Watch it online free on ZapFlix.