Slayers
Follows the exploits of the young sorceress Lina Inverse, whose life revolves around food, treasure, and fighting. After stealing treasure from a group of bandits, Lina is accosted by stragglers during her journey to the next town. She's not in any real danger, but a dim-witted but good-natured swordsman named Gourry Gabriev springs to her rescue anyways. The two team up, and head to Atlas City, fighting foes they encounter on the way. Unbeknownst to them, two mysterious figures are hot on their tail, and they are especially interested in the “treasure” Lina and Gourry have stolen.

Season 3 · Episode 25 ·
He Who Emerges from the Dark Star!
Valgaav reveals both the Dark Lord, Dark Star, and the God, Vophied, wanted to purify the world. In doing so, they would recreate everything, meaning killing everyone and starting over. Lina and the gang tries to fight him, but a Dragon Slave would not work. Valgaav tries to talk to them, but moves onto another location.
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Episode 25 of season 3 of Slayers: “He Who Emerges from the Dark Star!”. Aired 1997-09-19. Watch it online free on ZapFlix.