Durarara!!
Mikado Ryugamine moves to Ikebukuro at his friend’s invitation and quickly becomes entangled in the city’s dangerous underworld. After witnessing the legendary Headless Rider, he finds himself caught up in escalating violence and gang conflict that begin to throw Ikebukuro into chaos.

Season 1 · Episode 2 ·
Highly Unpredictable
It is the Entrance Ceremony at Raira Academy, and the auditorium swells with a varied mix of emotions emitted from the students. Amidst all this is Rio Kamichika: a girl with a notably dark vibe following her.
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Episode 2 of season 1 of Durarara!!: “Highly Unpredictable”. Aired 2010-01-15. Watch it online free on ZapFlix.