Fate/Zero
The Fourth Holy Grail War has begun, and seven mages must summon heroes from history to battle each other to the death. Only one mage-and-hero pair will remain to claim the Grail and have their wishes granted! Kiritsugu Emiya was once an assassin but now fights in this war to save the world from those who would destroy it with the Grail’s power.

Season 1 · Episode 10 ·
Rin's Big Adventure
The mystery of the mass kidnappings in Fuyuki remains unsolved, with more kids disappearing daily. When Tohsaka Rin can't get in touch with her friend Kotone, she braves the darkness and enters the city on her own to search for her. That's when she spots a strange man leading two kids around and decides to follow him...
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Episode 10 of season 1 of Fate/Zero: “Rin's Big Adventure”. Aired 2011-12-04. Watch it online free on ZapFlix.