Penguindrum
A terminally ill girl named Himari Takakura is miraculously saved from death by a strange spirit who resides in a penguin-shaped hat. However, in exchange for extending her life, the spirit tasks Himari's brothers, Kanba and Shōma, to seek out an elusive item known as the Penguin Drum with assistance from a trio of strange penguins.

Season 1 · Episode 20 ·
Thank You for Choosing Me
Masako decides to leave the Takakuras alone, still not accepting the 'family' they have. As Himari has another conversation with Sanetoshi, Shouma confesses to Ringo that Himari is not actually his blood sister. Years ago, whilst his parents were organising to change the world with their organization, Shouma met the orphaned Himari whilst exploring his condo. Whilst she is initially passive of him, the two grew a friendship over an abandoned kitten they find, up until it ended up being taken away. When Shouma discovered that Himari had headed over to the 'Child Broiler', where unneeded children go to disappear from the world, he rushed over there to rescue her and chose her to become a part
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Episode 20 of season 1 of Penguindrum: “Thank You for Choosing Me”. Aired 2011-11-25. Watch it online free on ZapFlix.