Fairy Tail
Lucy is a 17-year-old girl, who wants to be a full-fledged mage. One day when visiting Harujion Town, she meets Natsu, a young man who gets sick easily by any type of transportation. But Natsu isn't just any ordinary kid, he's a member of one of the world's most infamous mage guilds: Fairy Tail.

Season 2 · Episode 16 ·
Zero
Erza manages to overcome Midnight's illusory magic, while Natsu, Gray, Lucy and Happy confront Brain's staff, Klodoa. Realizing Midnight's defeat, Klodoa explains that Brain has an alternate destructive personality called Zero that was kept sealed by the members of the Oración Seis using body link magic. The seal is released and Zero emerges and defeats Natsu, Grey, Lucy and Happy with ease. Erza, Jellal, Wendy and Charle make haste as Zero initiates Nirvana to fire upon Cait Shelter.
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Episode 16 of season 2 of Fairy Tail: “Zero”. Aired 2011-01-31. Watch it online free on ZapFlix.