Hart to Hart
Wealthy couple Jonathan and Jennifer Hart, a self-made millionaire and his journalist wife, moonlight as amateur detectives.

Season 2 · Episode 1 ·
Murder, Murder on the Wall
When a bridegroom disappears abruptly and leaves his wife, who is an acquaintance of Jennifer's, to face a couple of thugs by herself, the Harts step in to help her.
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Episode 1 of season 2 of Hart to Hart: “Murder, Murder on the Wall”. Aired 1980-11-11. Watch it online free on ZapFlix.