Hart to Hart
Wealthy couple Jonathan and Jennifer Hart, a self-made millionaire and his journalist wife, moonlight as amateur detectives.

Season 3 · Episode 8 ·
Hart of Darkness
A psychotic man pours a blinding chemical into the Harts pool. Seconds after Jonathan dives in for his morning swim, he surfaces, screaming in pain.
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Episode 8 of season 3 of Hart to Hart: “Hart of Darkness”. Aired 1981-12-08. Watch it online free on ZapFlix.