Zatch Bell!
Takamine Kiyomaro, a depressed don't-care-about-the-world guy, was suddenly given a little demon named Zatch Bell to take care of. Little does he know that Zatch is embroiled in an intense fight to see who is the ruler of the demon world.

Season 1 · Episode 30 ·
Zatch and Tia: A Fierce Combination
At the amusement park, Kiyo and Zatch battle against the enemy tag team of Lupa and Purio and Hige and Zoboron, then Megumi and Tia arrive on the scene and it becomes a battle of 4 against 4.
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Episode 30 of season 1 of Zatch Bell!: “Zatch and Tia: A Fierce Combination”. Aired 2003-11-02. Watch it online free on ZapFlix.