Zatch Bell!
Takamine Kiyomaro, a depressed don't-care-about-the-world guy, was suddenly given a little demon named Zatch Bell to take care of. Little does he know that Zatch is embroiled in an intense fight to see who is the ruler of the demon world.

Season 1 · Episode 50 ·
The Sixth Spell
Kiyo and Zatch are accosted by Dr. Riddles and Kido, who use odd tactics to try to defeat our heroes. After a number of confusing riddles and puzzles, the two human/mamodo teams finally battle it out. But it seems that Dr. Riddles has learned the ins and outs of the spell book!
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Episode 50 of season 1 of Zatch Bell!: “The Sixth Spell”. Aired 2004-03-28. Watch it online free on ZapFlix.