Bewitched
Samantha Stephens is a seemingly normal suburban housewife who also happens to be a genuine witch, with all the requisite magical powers. Her husband Darrin insists that Samantha keep her witchcraft under wraps, but situations invariably require her to indulge her powers while keeping her bothersome mother Endora at bay.

Season 4 · Episode 4 ·
Double, Double, Toil and Trouble
Endora is fed up. Samantha's loyalty to her marriage is keeping her from her responsibilities as Queen of the Witches. While Samantha is out, Endora calls Serena to impersonate Sam and make a shambles of their marriage. Darrin finally realizes that it is Serena, and plans on turning the tables--only the real Samantha has arrived home.
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Episode 4 of season 4 of Bewitched: “Double, Double, Toil and Trouble”. Aired 1967-09-28. Watch it online free on ZapFlix.