Bleach
For as long as he can remember, Ichigo Kurosaki has been able to see ghosts. But when he meets Rukia, a Soul Reaper who battles evil spirits known as Hollows, he finds his life is changed forever. Now, with a newfound wealth of spiritual energy, Ichigo discovers his true calling: to protect the living and the dead from evil.

Season 1 · Episode 190 ·
Hueco Mundo Chapter, Restart!
Following a lengthy recap of the events since Sōsuke Aizen betrayed Soul Society, Ichigo Kurosaki concludes his duel with Grimmjow Jaegerjaquez before being confronted by Nnoitra Gilga.
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Episode 190 of season 1 of Bleach: “Hueco Mundo Chapter, Restart!”. Aired 2008-10-14. Watch it online free on ZapFlix.