Bleach
For as long as he can remember, Ichigo Kurosaki has been able to see ghosts. But when he meets Rukia, a Soul Reaper who battles evil spirits known as Hollows, he finds his life is changed forever. Now, with a newfound wealth of spiritual energy, Ichigo discovers his true calling: to protect the living and the dead from evil.

Season 1 · Episode 40 ·
The Shinigami whom Ganju Met
While 11th Division Lieutenant Yachiru Kusajishi reminisces about her history with her captain, Kenpachi Zaraki, Ganju Shiba and 4th Division 7th Seat Hanatarō Yamada reach Rukia Kuchiki's cell in Senzaikyū.
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Episode 40 of season 1 of Bleach: “The Shinigami whom Ganju Met”. Aired 2005-07-12. Watch it online free on ZapFlix.