Bleach
For as long as he can remember, Ichigo Kurosaki has been able to see ghosts. But when he meets Rukia, a Soul Reaper who battles evil spirits known as Hollows, he finds his life is changed forever. Now, with a newfound wealth of spiritual energy, Ichigo discovers his true calling: to protect the living and the dead from evil.

Season 1 · Episode 82 ·
Ichigo vs. Dalk! Appearance of the Faded Darkness
6th Division Lieutenant Renji Abarai fights off the Bitto, who are quickly recalled, while Ichigo Kurosaki battles Gō Koga's Doll, Dalk, in her new form.
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Episode 82 of season 1 of Bleach: “Ichigo vs. Dalk! Appearance of the Faded Darkness”. Aired 2006-05-30. Watch it online free on ZapFlix.