Bleach
For as long as he can remember, Ichigo Kurosaki has been able to see ghosts. But when he meets Rukia, a Soul Reaper who battles evil spirits known as Hollows, he finds his life is changed forever. Now, with a newfound wealth of spiritual energy, Ichigo discovers his true calling: to protect the living and the dead from evil.

Season 1 · Episode 240 ·
Byakuya's Betrayal
Ichigo Kurosaki attacks Muramasa, but Senbonzakura, and later 6th Division Captain Byakuya Kuchiki, shows up to protect him.
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Episode 240 of season 1 of Bleach: “Byakuya's Betrayal”. Aired 2009-10-06. Watch it online free on ZapFlix.