Bleach
For as long as he can remember, Ichigo Kurosaki has been able to see ghosts. But when he meets Rukia, a Soul Reaper who battles evil spirits known as Hollows, he finds his life is changed forever. Now, with a newfound wealth of spiritual energy, Ichigo discovers his true calling: to protect the living and the dead from evil.

Season 1 · Episode 242 ·
Shinigami and Zanpakutō, Total Sortie
As Ichigo Kurosaki, 2nd Division Captain Suì-Fēng, and 3rd Division Lieutenant Izuru Kira begin their battles, 11th Division 3rd Seat Ikkaku Madarame fights and defeats his Zanpakutō Spirit, Hōzukimaru.
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Episode 242 of season 1 of Bleach: “Shinigami and Zanpakutō, Total Sortie”. Aired 2009-10-20. Watch it online free on ZapFlix.