Bleach
For as long as he can remember, Ichigo Kurosaki has been able to see ghosts. But when he meets Rukia, a Soul Reaper who battles evil spirits known as Hollows, he finds his life is changed forever. Now, with a newfound wealth of spiritual energy, Ichigo discovers his true calling: to protect the living and the dead from evil.

Season 1 · Episode 271 ·
Ichigo Dies! Orihime, the Cry of Sorrow!
As Ichigo Kurosaki's Hollow form completely takes him over, he begins battling Ulquiorra Cifer again.
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Episode 271 of season 1 of Bleach: “Ichigo Dies! Orihime, the Cry of Sorrow!”. Aired 2010-05-18. Watch it online free on ZapFlix.