Totally Spies!
Totally Spies! depicts three girlfriends 'with an attitude' who have to cope with their daily lives at high school as well as the unpredictable pressures of international espionage. They confront the most intimidating - and demented - of villains, each with their own special agenda for demonic, global rude behavior.

Season 2 · Episode 23 ·
Starstruck
The girls talk Jerry into letting them have an unoffical mission to go undercover at a TV Studio to find the missing star of their favourite soap opera, "Spies Of Our Lives". Which turns out to be a lot more dangerous than they're expecting.
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Episode 23 of season 2 of Totally Spies!: “Starstruck”. Aired 2003-06-25. Watch it online free on ZapFlix.