Totally Spies!
Totally Spies! depicts three girlfriends 'with an attitude' who have to cope with their daily lives at high school as well as the unpredictable pressures of international espionage. They confront the most intimidating - and demented - of villains, each with their own special agenda for demonic, global rude behavior.

Season 4 · Episode 19 ·
Like, So Totally Not Spies (2)
The spies are sent to the moon to rescue a band. It's revealed the blame is the leader of band called Ziggy and he's beaten by the spies. In the b-story, because of her grades, Sam must graduate. Villain: Ziggy.
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Episode 19 of season 4 of Totally Spies!: “Like, So Totally Not Spies (2)”. Aired 2006-10-04. Watch it online free on ZapFlix.