Totally Spies!
Totally Spies! depicts three girlfriends 'with an attitude' who have to cope with their daily lives at high school as well as the unpredictable pressures of international espionage. They confront the most intimidating - and demented - of villains, each with their own special agenda for demonic, global rude behavior.

Season 4 · Episode 24 ·
Totally Busted (2)
A blond-haired jewel thief is about to plan a big jewelry heist on the special night Venus aligns with other planets, including Earth. The girls unfortunately fall for his dashing good looks, but realize after failing to catch him many times that they must put his handsomeness behind them and beat him at his own game. In the b-story, Sam won first place in the science-fair and now most of the nerds in Beverly High are chasing after her, demanding she sign t-shirts that have her face on them. Villain: Kyle Katz.
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Episode 24 of season 4 of Totally Spies!: “Totally Busted (2)”. Aired 2006-10-25. Watch it online free on ZapFlix.