Totally Spies!
Totally Spies! depicts three girlfriends 'with an attitude' who have to cope with their daily lives at high school as well as the unpredictable pressures of international espionage. They confront the most intimidating - and demented - of villains, each with their own special agenda for demonic, global rude behavior.

Season 4 · Episode 7 ·
Arnold The Great
Following a humiliation in the lunchroom, Arnold is left depressed. That night, as they watch someone breaking into an armoured van, Arnold dressed as a superhero appears, and attempts to capture the man. The van seals, and drives off a cliff. Sam, Clover, and Alex save Arnold beforehand, and make him swear to keep their identities secret. Geraldine Husk appears after the spies leave, and gives Arnold a utility belt. The next day, Arnold's superhero alter ego has been reported saving people, but the device is secretly brainwashing Arnold to destroy the spies. In a b story, Alex finds a stray puppy, and looks after him, as she attempts to find the owner. Villain: Geraldine Husk.
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Episode 7 of season 4 of Totally Spies!: “Arnold The Great”. Aired 2006-06-07. Watch it online free on ZapFlix.