Totally Spies!
Totally Spies! depicts three girlfriends 'with an attitude' who have to cope with their daily lives at high school as well as the unpredictable pressures of international espionage. They confront the most intimidating - and demented - of villains, each with their own special agenda for demonic, global rude behavior.

Season 3 · Episode 21 ·
Head Shrinker Much?
A villain who wants to be the most evolved and advanced person on the face of the planet invents a crazy device which physically shrinks peoples' brains, causing them to regress to a more primitive state. Essentially, he's turning everyone into cave men. As society becomes more primitive, the world (including Beverly Hills), begins to turn into a lawless Mad Max-type society. In a b-story, Sam takes ""charm"" lessons to impress an extremely cultured boy at school.
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Episode 21 of season 3 of Totally Spies!: “Head Shrinker Much?”. Aired 2005-05-18. Watch it online free on ZapFlix.