Spider-Man
Bitten by a neogenetic spider, Peter Parker develops spider-like superpowers. He uses these to fight crime while trying to balance it with the struggles of his personal life.

Season 1 · Episode 2 ·
The Spider Slayer (1)
Norman Osborn hires Spencer Smythe to design a machine capable of destroying Spider-Man—the Black Widow Spider Slayer. But when Flash Thompson puts on a Spider-Man costume as a party gag, the deadly machine spots him, and he's carried off in Peter's place.
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Episode 2 of season 1 of Spider-Man: “The Spider Slayer (1)”. Aired 1995-02-04. Watch it online free on ZapFlix.