Spider-Man
Bitten by a neogenetic spider, Peter Parker develops spider-like superpowers. He uses these to fight crime while trying to balance it with the struggles of his personal life.

Season 2 · Episode 1 ·
Neogenic Nightmare: The Insidious Six
The Crime Lords, led by Silvermane, are holding the Kingpin accountable for his failure to eliminate Spider-Man. So six of the wall-crawler's greatest enemies are called together to do the job: Doctor Octopus, Mysterio, the Scorpion, the Rhino, the Shocker and the Chameleon. Unfortunately, Spidey's powers have been on the blink due to the changes in his blood chemistry.
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Episode 1 of season 2 of Spider-Man: “Neogenic Nightmare: The Insidious Six”. Aired 1995-09-09. Watch it online free on ZapFlix.