Spider-Man
Bitten by a neogenetic spider, Peter Parker develops spider-like superpowers. He uses these to fight crime while trying to balance it with the struggles of his personal life.

Season 4 · Episode 5 ·
Partners in Danger: Partners
While settling in to her new role as a hero, the Black Cat is captured by Alistair Smythe, now working for Silvermane, who is trapped in the body of a baby. Smythe delivers Spider-Man an ultimatum: capture the Scorpion or the Vulture within 24 hours, or the Black Cat dies.
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Episode 5 of season 4 of Spider-Man: “Partners in Danger: Partners”. Aired 1997-05-03. Watch it online free on ZapFlix.