Spider-Man
Bitten by a neogenetic spider, Peter Parker develops spider-like superpowers. He uses these to fight crime while trying to balance it with the struggles of his personal life.

Season 5 · Episode 3 ·
Six Forgotten Warriors (2): Unclaimed Legacy
Still in Russia, Peter discovers that searching for clues to his family's past isn't easy when he has to battle the Insidious Six and the Red Skull.
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Episode 3 of season 5 of Spider-Man: “Six Forgotten Warriors (2): Unclaimed Legacy”. Aired 1997-09-26. Watch it online free on ZapFlix.