Spider-Man
Bitten by a neogenetic spider, Peter Parker develops spider-like superpowers. He uses these to fight crime while trying to balance it with the struggles of his personal life.

Season 1 · Episode 4 ·
Doctor Octopus: Armed and Dangerous
Dr. Otto Octavius becomes the mad Dr. Octopus when his robotic arms become fused to him in a laboratory accident. He then seeks revenge for the humiliation the Hardy Foundation has caused him, so he kidnaps Felicia Hardy and holds her ransom.
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Episode 4 of season 1 of Spider-Man: “Doctor Octopus: Armed and Dangerous”. Aired 1995-02-18. Watch it online free on ZapFlix.