Spider-Man
Bitten by a neogenetic spider, Peter Parker develops spider-like superpowers. He uses these to fight crime while trying to balance it with the struggles of his personal life.

Season 3 · Episode 8 ·
The Sins of the Fathers: The Ultimate Slayer
Worried that the Kingpin is going to eliminate him after the botched framing of Peter Parker, Alistair Smythe arranges a meeting with Spider-Man to give him information about the Kingpin. When Spider-Man arrives, he discovers Smythe has been turned into a spider-slaying cyborg. However, when his programming malfunctions, he goes after the man he feels responsible for his father's death, Norman Osborn. Peter must fight a crazed Smythe, as well as his feelings, after he discovers Mary Jane, the woman he loves, and Harry, his best friend, are engaged.
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Episode 8 of season 3 of Spider-Man: “The Sins of the Fathers: The Ultimate Slayer”. Aired 1996-10-05. Watch it online free on ZapFlix.