Dexter's Laboratory
Dexter, a boy-genius with a secret laboratory, constantly battles his sister Dee Dee, who always gains access despite his best efforts to keep her out, as well as his arch-rival and neighbor, Mandark.

Season 2 · Episode 100 ·
Blackfoot and Slim
A documentary shows the secret lives of Dexter and Dee Dee, also known as Blackfoot and Slim.
108 episodes
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Episode 100 of season 2 of Dexter's Laboratory: “Blackfoot and Slim”. Aired 1998-04-22. Watch it online free on ZapFlix.