Dexter's Laboratory
Dexter, a boy-genius with a secret laboratory, constantly battles his sister Dee Dee, who always gains access despite his best efforts to keep her out, as well as his arch-rival and neighbor, Mandark.

Season 4 · Episode 15 ·
Used Ink
Dexter creates an ink in which lets him command them to do whatever he wants them to do. Although when Mandark gets a hold of it, Dexter is the one being the slave.
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Episode 15 of season 4 of Dexter's Laboratory: “Used Ink”. Aired 2003-05-16. Watch it online free on ZapFlix.