Dexter's Laboratory
Dexter, a boy-genius with a secret laboratory, constantly battles his sister Dee Dee, who always gains access despite his best efforts to keep her out, as well as his arch-rival and neighbor, Mandark.
Season 2 · Episode 7 ·
D & DD
When Dexter's friends tire of the complicated traps he sets up as Dungeon Master (he has their character's killed every time), they put Dee Dee in charge for a change of pace.
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Episode 7 of season 2 of Dexter's Laboratory: “D & DD”. Aired 1997-07-30. Watch it online free on ZapFlix.