Dexter's Laboratory
Dexter, a boy-genius with a secret laboratory, constantly battles his sister Dee Dee, who always gains access despite his best efforts to keep her out, as well as his arch-rival and neighbor, Mandark.

Season 2 · Episode 3 ·
Ant Pants
Dexter prevents Dee Dee from destroying some ants. In order to teach her about ants, Dexter and Dee enter Dexter's ant farm. The ants think Dexter is a criminal and has him fight to the death with a stronger ant.
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Episode 3 of season 2 of Dexter's Laboratory: “Ant Pants”. Aired 1997-07-16. Watch it online free on ZapFlix.