Dexter's Laboratory
Dexter, a boy-genius with a secret laboratory, constantly battles his sister Dee Dee, who always gains access despite his best efforts to keep her out, as well as his arch-rival and neighbor, Mandark.

Season 2 · Episode 18 ·
Labels
Dexter and Dee Dee label everything in the house. When their parents get home, they mistake Dexter for Dee Dee (he had a Dee Dee label on his forehead), but he already blamed Dee Dee for the chaos.
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Episode 18 of season 2 of Dexter's Laboratory: “Labels”. Aired 1997-08-27. Watch it online free on ZapFlix.