Dexter's Laboratory
Dexter, a boy-genius with a secret laboratory, constantly battles his sister Dee Dee, who always gains access despite his best efforts to keep her out, as well as his arch-rival and neighbor, Mandark.

Season 2 · Episode 30 ·
Road Rash
Mom makes Dexter go outside and ride a bike, thing that turns into a Dexter-Dee Dee chase.
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Episode 30 of season 2 of Dexter's Laboratory: “Road Rash”. Aired 1997-09-24. Watch it online free on ZapFlix.