Dexter's Laboratory
Dexter, a boy-genius with a secret laboratory, constantly battles his sister Dee Dee, who always gains access despite his best efforts to keep her out, as well as his arch-rival and neighbor, Mandark.

Season 2 · Episode 6 ·
That Crazy Robot
One of Dexter's robots becomes Dee Dee's servant when she removes a wrench that froze him up, but the robot is willing to destroy anyone who is mean to her or scolds her, including Dexter.
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Episode 6 of season 2 of Dexter's Laboratory: “That Crazy Robot”. Aired 1997-07-23. Watch it online free on ZapFlix.